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產(chǎn)品詳情

  • 產(chǎn)品名稱(chēng)：PBDD4T CAS:1439937-09-3

  • 產(chǎn)品型號(hào)：PBDD4T CAS:1439937-09-3
  • 產(chǎn)品廠商：Ossila
  • 產(chǎn)品價(jià)格：0
  • 折扣價(jià)格：0
  • 產(chǎn)品文檔：
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簡(jiǎn)單介紹：
High purity and high molecular weight - PBDD4T is purified by Soxhlet extraction with methanol, hexane and chloroform under an argon atmosphere Batch-specific GPC data - so you have confidence in what you are ordering. Also, GPC data is always convenient for your thesis and publications Large-quantity orders - so you can plan your experiments with polymers from the same batch
詳情介紹：

Luminosyn? PBDD4T is now available, featuring:

  • High purity and high molecular weight - PBDD4T is purified by Soxhlet extraction with methanol, hexane and chloroform under an argon atmosphere
  • Batch-specific GPC data - so you have confidence in what you are ordering. Also, GPC data is always convenient for your thesis and publications
  • Large-quantity orders - so you can plan your experiments with polymers from the same batch

Pricing

Batch Quantity
M2049A1 100 mg
M2049A1 250 mg
M2049A1 500 mg
M2049A1 1 g
M2049A1 5 - 10 g*

 *for 5-10 grams order quantity, the lead time is 4-6 weeks.

Batch details

Batch Mw Mn PDI
M2049A1 112,851 49,310 2.29

 

General Information

Full name Poly[[5,7-bis(2-ethylhexyl)-4,8-dioxo-4H,8H-benzo[1,2-c:4,5-c']dithiophene-1,3-diyl][3,3'''-bis(2-ethylhexyl)[2,2':5',2'':5'',2'''-quaterthiophene]-5,5'''-diyl]]
Synonyms PBT1, BDD4T
Chemical formula (C58H74O2S6)n
CAS number 1439937-09-3
Solubility Chloroform, chlorobenzene and dichlorobenzene
HOMO / LUMO HOMO = -5.30 eV, Eg = 1.76 eV [1]
Classification / Family Polythiophenes, Organic n-type semiconducting materials, Organic photovoltaics, Polymer solar cells, Tandem solar cells, Electron-acceptor polymers, OFETs, Perovskite solar cells, All-polymer solar cells.
Solubility Soluble in chloroform, chlorobenzene, dichlorobenzene
pbdd4t, PBT1, BDD4T chemical structure
Chemical structure and product image of PBDD4T; Chemical formula: (C58H74O2S6)n.

Applications

As a family member of polythiophenes, PBDD4T has a backbone consisting of repeating benzodithiophene-4,8-dione and α-quaterthiophene units. π electrons can be delocalized effectively through the alternative electron push?pull effect, resulting a low band-gap polymer. Also, with four ethylhexyl branched side chains, the polymer is more soluble in most of organic solvents.

We also have PBDD4T-2F available which allows fluorine-fluorine interaction at the polymer back-bone structure for device film morphology control. Both PBDD4T and PBDD4T-2F are used for highly efficient fullerene and non-fullerene including such as ITIC and P(NDI2OD-T2F) as acceptors for OPV devices.

Literature and Reviews

  1. A Fluorinated Polythiophene Derivative with Stabilized Backbone Conformation for Highly Efficient Fullerene and Non-Fullerene Polymer Solar Cells, S. Zhang et al., Macromolecules, 49 (8), 2993–3000 (2016); DOI: 10.1021/acs.macromol.6b00248.
  2. Molecular Design toward Efficient Polymer Solar Cells with High Polymer Content, D. Qian et al., J. Am. Chem. Soc., 2013, 135 (23), 8464–8467 (2013); DOI: 10.1021/ja402971d.
  3. Toward reliable and accurate evaluation of polymer solar cells based on low band gap polymers, L. Ye et al., J. Mater. Chem. C, 3, 564-569 (2015); DOI: 10.1039/C4TC02449D.
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